Salt metathesis in three dimensional metal–organic frameworks (MOFs) with unprecedented hydrolytic regenerability†
Abstract
Eight Zn-based porous (1.2 nm) homochiral MOFs (ValZnX, AlaZnX, X = Cl−, Br−, HCO2− and CH3CO2−) were synthesized which possess extremely rare zeolitic (unh) topology. These MOFs show an unprecedented hydrolytic regenerability. Salt