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Issue 46, 2013
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Reversible dioxygen binding on asymmetric dinuclear rhodium centres

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Abstract

Electron-deficient dinuclear rhodium complexes [Rh2Cl2(μ-dpmppp)(RNC)] (1), with the linear tetraphosphine ligand dpmppp, showed reversible binding of molecular oxygen to form asymmetric dirhodium η2-peroxo complexes [Rh2Cl2(O2)(μ-dpmppp)(RNC)] (2) stabilized by a Rh→Rh dative bond.

Graphical abstract: Reversible dioxygen binding on asymmetric dinuclear rhodium centres

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Publication details

The article was received on 11 Mar 2013, accepted on 28 Mar 2013 and first published on 02 Apr 2013


Article type: Communication
DOI: 10.1039/C3CC41815D
Citation: Chem. Commun., 2013,49, 5250-5252
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    Reversible dioxygen binding on asymmetric dinuclear rhodium centres

    T. Nakajima, M. Sakamoto, S. Kurai, B. Kure and T. Tanase, Chem. Commun., 2013, 49, 5250
    DOI: 10.1039/C3CC41815D

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