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Issue 41, 2013
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Metalated nitriles: N- and C-coordination preferences of Li, Mg, and Cu cations

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Abstract

13C NMR analyses of a series of metalated arylacetonitriles and cyclohexanecarbonitriles with the synthetically relevant metals Li, Mg, and Cu identifies the influence of the carbon scaffold and the nature of the metal on the preference for N- or C-metalation.

Graphical abstract: Metalated nitriles: N- and C-coordination preferences of Li, Mg, and Cu cations

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Publication details

The article was received on 06 Mar 2013, accepted on 04 Apr 2013 and first published on 15 Apr 2013


Article type: Communication
DOI: 10.1039/C3CC41703D
Citation: Chem. Commun., 2013,49, 4700-4702
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    Metalated nitriles: N- and C-coordination preferences of Li, Mg, and Cu cations

    M. Purzycki, W. Liu, G. Hilmersson and F. F. Fleming, Chem. Commun., 2013, 49, 4700
    DOI: 10.1039/C3CC41703D

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