Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Tuesday 6th February 2018 from 11.00am to 11.15am (GMT).

During this time our website performance may be temporarily affected. If you have any questions please use the feedback button available under our menu button. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 41, 2013
Previous Article Next Article

Pd-catalyzed diastereoselective allylation of aldehydes with 3-bromomethyl-5H-furan-2-one: stereoselective synthesis of β-(hydroxymethylaryl/alkyl)-α-methylene-γ-butyrolactones with a syn configuration

Author affiliations

Abstract

An efficient and diastereoselective Pd-catalyzed method of allylation of aldehydes with 3-bromomethyl-5H-furan-2-one is described. The proposed method allows the synthesis of β-(hydroxymethylaryl/alkyl)-α-methylene-γ-butyrolactones with a syn relative configuration for the first time.

Graphical abstract: Pd-catalyzed diastereoselective allylation of aldehydes with 3-bromomethyl-5H-furan-2-one: stereoselective synthesis of β-(hydroxymethylaryl/alkyl)-α-methylene-γ-butyrolactones with a syn configuration

Back to tab navigation

Supplementary files

Publication details

The article was received on 28 Feb 2013, accepted on 03 Apr 2013 and first published on 05 Apr 2013


Article type: Communication
DOI: 10.1039/C3CC41501E
Citation: Chem. Commun., 2013,49, 4697-4699
  •   Request permissions

    Pd-catalyzed diastereoselective allylation of aldehydes with 3-bromomethyl-5H-furan-2-one: stereoselective synthesis of β-(hydroxymethylaryl/alkyl)-α-methylene-γ-butyrolactones with a syn configuration

    F. Zhang, Y. Yang, L. Xie and X. Xu, Chem. Commun., 2013, 49, 4697
    DOI: 10.1039/C3CC41501E

Search articles by author

Spotlight

Advertisements