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Issue 36, 2013
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C60-Bodipy dyad triplet photosensitizers as organic photocatalysts for photocatalytic tandem oxidation/[3+2] cycloaddition reactions to prepare pyrrolo[2,1-a]isoquinoline

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Abstract

C60-Bodipy hybrids exhibiting strong absorption of visible light and long-lived triplet excited states were used as photocatalysts for tandem oxidation/[3+2] cycloaddition of tetrahydroisoquinoline with N-phenylmaleimide to produce pyrrolo[2,1-a]isoquinolines. The reaction is substantially accelerated, compared to that catalyzed by Ru(bpy)3Cl2.

Graphical abstract: C60-Bodipy dyad triplet photosensitizers as organic photocatalysts for photocatalytic tandem oxidation/[3+2] cycloaddition reactions to prepare pyrrolo[2,1-a]isoquinoline

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Publication details

The article was received on 27 Feb 2013, accepted on 18 Mar 2013 and first published on 18 Mar 2013


Article type: Communication
DOI: 10.1039/C3CC41494A
Citation: Chem. Commun., 2013,49, 3751-3753
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    C60-Bodipy dyad triplet photosensitizers as organic photocatalysts for photocatalytic tandem oxidation/[3+2] cycloaddition reactions to prepare pyrrolo[2,1-a]isoquinoline

    L. Huang and J. Zhao, Chem. Commun., 2013, 49, 3751
    DOI: 10.1039/C3CC41494A

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