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Issue 34, 2013
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Multielectron transfer in a dicopper(II) anthraquinophane

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Abstract

The new dinuclear copper(II) metallacyclophane with the non-innocent N,N′-1,4-bis(oxamate)-9,10-anthraquinone bridging ligand possesses a dual multielectron redox behavior featuring stepwise one-electron oxidation of the antiferromagnetically coupled CuII ions and two-electron reduction of the anthraquinone spacers in a π-stacked anti conformation.

Graphical abstract: Multielectron transfer in a dicopper(ii) anthraquinophane

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Publication details

The article was received on 25 Feb 2013, accepted on 11 Mar 2013 and first published on 13 Mar 2013


Article type: Communication
DOI: 10.1039/C3CC41434E
Citation: Chem. Commun., 2013,49, 3534-3536
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    Multielectron transfer in a dicopper(II) anthraquinophane

    M. Castellano, R. Ruiz-García, J. Cano, M. Julve, F. Lloret, Y. Journaux, G. De Munno and D. Armentano, Chem. Commun., 2013, 49, 3534
    DOI: 10.1039/C3CC41434E

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