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Issue 36, 2013
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Micro-flowers changing to nano-bundle aggregates by translocation of the sugar moiety in Janus TA nucleosides

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Abstract

We designed and synthesized the Janus-type TA nucleosides (1–3) by using a transglycosylation protocol. Surprisingly, the subtle translocation of the ribose from N8 to N1 by about 230 pm in space leads to the formation of entirely different shaped superstructures, micro-flowers for J-AT and nano-bundles for J-TA.

Graphical abstract: Micro-flowers changing to nano-bundle aggregates by translocation of the sugar moiety in Janus TA nucleosides

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Publication details

The article was received on 18 Jan 2013, accepted on 04 Mar 2013 and first published on 06 Mar 2013


Article type: Communication
DOI: 10.1039/C3CC41383G
Citation: Chem. Commun., 2013,49, 3742-3744
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    Micro-flowers changing to nano-bundle aggregates by translocation of the sugar moiety in Janus TA nucleosides

    H. Zhao, S. He, M. Yang, X. Guo, G. Xin, C. Zhang, L. Ye, L. Chu, Z. Xing, W. Huang, Q. Chen and Y. He, Chem. Commun., 2013, 49, 3742
    DOI: 10.1039/C3CC41383G

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