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Issue 57, 2013
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Synthesis of pseudo-indoxyl derivatives via sequential Cu-catalyzed SNAr and Smalley cyclization

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Abstract

ortho-Bromophenyl sec-alkyl/sec-alkenyl ketones, on reaction with sodium azide in the presence of copper salts, undergo sequential SNAr followed by Smalley cyclization to provide pseudo-indoxyl derivatives. Some of these pseudo-indoxyl derivatives exhibit interesting fluorescent properties and broad Stokes shifts.

Graphical abstract: Synthesis of pseudo-indoxyl derivatives via sequential Cu-catalyzed SNAr and Smalley cyclization

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Publication details

The article was received on 21 Feb 2013, accepted on 04 Apr 2013 and first published on 05 Apr 2013


Article type: Communication
DOI: 10.1039/C3CC41348A
Citation: Chem. Commun., 2013,49, 6376-6378
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    Synthesis of pseudo-indoxyl derivatives via sequential Cu-catalyzed SNAr and Smalley cyclization

    Y. Goriya and C. V. Ramana, Chem. Commun., 2013, 49, 6376
    DOI: 10.1039/C3CC41348A

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