CuBr2-catalyzed decarboxylative acylation of the acyl C–H of N-monosubstituted and N,N-disubstituted formamides with α-oxocarboxylic acids leading to α-ketoamides was developed, which generated the corresponding products in good yields.
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Cu(II)-catalyzed decarboxylative acylation of acyl C–H of formamides with α-oxocarboxylic acids leading to α-ketoamides
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a
Department of Chemistry, Huaibei Normal University, Huaibei, P. R. China
E-mail: leiwang@chnu.edu.cn ;
Fax: +86-561-309-0518 ;
Tel: +86-561-380-2069
E-mail: leiwang@chnu.edu.cn ;
Fax: +86-561-309-0518 ;
Tel: +86-561-380-2069
b
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, P. R. China
Chem. Commun., 2013,49, 3640-3642
DOI: 10.1039/C3CC41188E
Received 13 Feb 2013, Accepted 12 Mar 2013
First published online 14 Mar 2013
Chemical Communications
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