Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Tuesday 6th February 2018 from 11.00am to 11.15am (GMT).

During this time our website performance may be temporarily affected. If you have any questions please use the feedback button available under our menu button. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 46, 2013
Previous Article Next Article

An alternately introduced heterometallo-supramolecular polymer: synthesis and solid-state emission switching by electrochemical redox

Author affiliations

Abstract

By utilizing different coordination properties of a lanthanide ion and a transition metal ion, a heterometallo-supramolecular polymer with Eu(III) and Fe(II) ions introduced alternately (polyEuFe) was precisely prepared via stepwise complexation of the metal ions to a new unsymmetrical ligand with both a dicarboxylate-substituted terpyridine and an unsubstituted terpyridine. The polymer showed unique, reversible “on–off” switching of the Eu(III) luminescence by electrochemical redox of the Fe ions in the solid-state.

Graphical abstract: An alternately introduced heterometallo-supramolecular polymer: synthesis and solid-state emission switching by electrochemical redox

Back to tab navigation

Supplementary files

Publication details

The article was received on 13 Feb 2013, accepted on 21 Mar 2013 and first published on 21 Mar 2013


Article type: Communication
DOI: 10.1039/C3CC41176A
Citation: Chem. Commun., 2013,49, 5256-5258
  •   Request permissions

    An alternately introduced heterometallo-supramolecular polymer: synthesis and solid-state emission switching by electrochemical redox

    T. Sato and M. Higuchi, Chem. Commun., 2013, 49, 5256
    DOI: 10.1039/C3CC41176A

Search articles by author

Spotlight

Advertisements