Remarkable cage deboronation and rearrangement of a closo-1,12-dicarbadodecaborane to form a neutral nido-7,9-dicarbaundecaborane

Joseph A. Ioppolo; Mohan Bhadbhade; Mark A. Fox; Louis M. Rendina

doi:10.1039/C3CC41173G

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Chemical Communications

Issue 32, 2013

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Remarkable cage deboronation and rearrangement of a closo-1,12-dicarbadodecaborane to form a neutral nido-7,9-dicarbaundecaborane

Joseph A. Ioppolo,^a Mohan Bhadbhade,^b Mark A. Fox*^c and Louis M. Rendina*^a

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School of Chemistry, The University of Sydney, Sydney, Australia
E-mail: lou.rendina@sydney.edu.au ;
Fax: +61 2 9351 3329

Solid State and Elemental Analysis Unit, The University of New South Wales, Kensington, Australia

Department of Chemistry, Durham University, South Road, Durham DH1 3LE, UK
E-mail: m.a.fox@durham.ac.uk ;
Fax: +44 (0)191 334 2051

Chem. Commun., 2013,49, 3312-3314

DOI: 10.1039/C3CC41173G
Received 13 Feb 2013, Accepted 04 Mar 2013
First published online 14 Mar 2013

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Deboronation and cage rearrangement of the closo-1,12-carborane salt [1,12-(PPh₂Me)₂-1,12-C₂B₁₀H₁₀]I₂ occurs in refluxing methanol to give the zwitterionic nido-7,9-carborane 7,9-(PPh₂Me)₂-7,9-C₂B₉H₉. Notably, deboronation and cage substitution of the isomeric closo-1,7-carborane salt [1,7-(PPh₂Me)₂-1,7-C₂B₁₀H₁₀]I₂ takes place in methanol to afford the salt [10-OMe-7,9-(PPh₂Me)₂-7,9-C₂B₉H₉]I.

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Remarkable cage deboronation and rearrangement of a closo-1,12-dicarbadodecaborane to form a neutral nido-7,9-dicarbaundecaborane

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Remarkable cage deboronation and rearrangement of a closo-1,12-dicarbadodecaborane to form a neutral nido-7,9-dicarbaundecaborane

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