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Issue 28, 2013
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Synthesis of highly substituted oxetanes via [2+2] cycloaddition reactions of allenoates catalyzed by a guanidine Lewis base

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Abstract

The first synthesis of highly substituted 3-alkyl-oxetan-2-ylidenes from allenoates was developed by using the bicyclic guanidine 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) as an exceptionally active nitrogen Lewis base catalyst.

Graphical abstract: Synthesis of highly substituted oxetanes via [2+2] cycloaddition reactions of allenoates catalyzed by a guanidine Lewis base

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Publication details

The article was received on 31 Jan 2013, accepted on 20 Feb 2013 and first published on 22 Feb 2013


Article type: Communication
DOI: 10.1039/C3CC40855H
Citation: Chem. Commun., 2013,49, 2930-2932
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    Synthesis of highly substituted oxetanes via [2+2] cycloaddition reactions of allenoates catalyzed by a guanidine Lewis base

    P. Selig, A. Turočkin and W. Raven, Chem. Commun., 2013, 49, 2930
    DOI: 10.1039/C3CC40855H

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