Issue 26, 2013
From the journal:

Chemical Communications

The cubic [Ti8F36]4− anion found in the crystal structures of K4Ti8F36·8HF and Rb4Ti8F36·6HF†

Igor M. Shlyapnikov,*a   Evgeny A. Goreshnika  and  Zoran Mazej*a  

* Corresponding authors

a Department of Inorganic Chemistry and Technology, Jožef Stefan Institute, Jamova 39, 1000 Ljubljana, Slovenia
E-mail: zoran.mazej@ijs.si, igor.shlyapnikov@ijs.si
Tel: +386 1 477 3301

Abstract

X-ray diffraction study of K4Ti8F36·8HF and Rb4Ti8F36·6HF reveals a novel type of octameric cubic [M8F36]4− anion built from eight MIVF6 octahedra.

Graphical abstract: The cubic [Ti8F36]4− anion found in the crystal structures of K4Ti8F36·8HF and Rb4Ti8F36·6HF

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Article information

DOI
https://doi.org/10.1039/C3CC40756J
Article type
Communication
Submitted
29 Jan 2013
Accepted
11 Feb 2013
First published
19 Feb 2013

Chem. Commun., 2013,49, 2703-2705

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The cubic [Ti8F36]4− anion found in the crystal structures of K4Ti8F36·8HF and Rb4Ti8F36·6HF

I. M. Shlyapnikov, E. A. Goreshnik and Z. Mazej, Chem. Commun., 2013, 49, 2703 DOI: 10.1039/C3CC40756J

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