An up to 18-fold increase of the turnover frequency (TOF) in the catalase-like hydrogen peroxide dismutation reaction is observed by incorporation of substituents in the β-position of xanthene-modified iron corroles.
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Synthesis of sterically hindered xanthene-modified iron corroles with catalase-like activity
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Department of Chemistry, Humboldt-Universität zu Berlin, Brook-Taylor-Str. 2, D-12489 Berlin, Germany
E-mail: matthias.schwalbe@hu-berlin.de ;
Fax: +49 30 2093 6966 ;
Tel: +49 30 2093 7571
E-mail: matthias.schwalbe@hu-berlin.de ;
Fax: +49 30 2093 6966 ;
Tel: +49 30 2093 7571
Chem. Commun., 2013,49, 3799-3801
DOI: 10.1039/C3CC40625C
Received 24 Jan 2013, Accepted 15 Mar 2013
First published online 15 Mar 2013
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