By understanding the structural relationship among three shape-controlled Rh nanostructures, namely, {111} nanotetrahedrons, {111} tetrahedral nanoframes, and 〈111〉 skeletal nanotetrapods, we could prepare novel hierarchical dendritic Rh nanostructures with 〈111〉 Rh arms as linkers between tetrahedral shaped nanocrystals.
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