Capture and metathesis-based release of potassium salts by a multitopic ion receptor

Sung Kuk Kim; Benjamin P. Hay; Jong Seung Kim; Bruce A. Moyer; Jonathan L. Sessler

doi:10.1039/C3CC39117E

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Chemical Communications

Issue 21, 2013

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Capture and metathesis-based release of potassium salts by a multitopic ion receptor

Sung Kuk Kim,^a Benjamin P. Hay,*^b Jong Seung Kim,*^c Bruce A. Moyer*^b and Jonathan L. Sessler*^a^d

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Department of Chemistry and Biochemistry, 105 E. 24th Street, Stop A5300, The University of Texas at Austin, Austin, USA
E-mail: sessler@cm.utexas.edu

Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, USA

Department of Chemistry, Korea University, Seoul 136-701, Korea

Department of Chemistry, Yonsei University, Seoul 120-749, Korea

Chem. Commun., 2013,49, 2112-2114

DOI: 10.1039/C3CC39117E
Received 20 Dec 2012, Accepted 24 Jan 2013
First published online 25 Jan 2013

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The multitopic ion-pair receptor 2 is able to recognize and extract various cesium and potassium salts via three different ion recognition modes. Furthermore, it is capable of extracting and then releasing KNO₃via ion-pair metathesis with CsClO₄, allowing KNO₃ recovery.

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Benjamin P. Hay
Jong Seung Kim
Bruce A. Moyer
Jonathan L. Sessler

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