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Issue 23, 2013
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100% thiol-functionalized ethylene PMOs prepared by “thiol acid–ene” chemistry

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Abstract

A novel thiol functionalized bis-silane PMO precursor was synthesized by highly efficient thiol acid–ene chemistry between the double bonds of 1,2-(E)-bis(triethoxysilyl)ethene and thioacetic acid. After aminolysis the self-assembly process of the formed SH-precursor with Pluronic P123 under acidic conditions yields the first 100% thiol–PMO material with good structural ordering.

Graphical abstract: 100% thiol-functionalized ethylene PMOs prepared by “thiol acid–ene” chemistry

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Publication details

The article was received on 19 Dec 2012, accepted on 01 Feb 2013 and first published on 04 Feb 2013


Article type: Communication
DOI: 10.1039/C3CC39074H
Citation: Chem. Commun., 2013,49, 2344-2346
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    100% thiol-functionalized ethylene PMOs prepared by “thiol acid–ene” chemistry

    D. Esquivel, O. van den Berg, F. J. Romero-Salguero, F. Du Prez and P. Van Der Voort, Chem. Commun., 2013, 49, 2344
    DOI: 10.1039/C3CC39074H

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