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[FeFe] hydrogenase active site modeling: a key intermediate bearing a thiolate proton and Fe hydride

Yu-Chiao Liu,a   Kai-Ti Chu,abc   Ruei-Lin Jhang,ad   Gene-Hsiang Leee and   Ming-Hsi Chiang*ab  
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Corresponding authors
a
Institute of Chemistry, Academia Sinica, Nankang, Taipei 115, Taiwan
E-mail: mhchiang@chem.sinica.edu.tw ;
Tel: +886-2-2789-8568
b
Molecular Science Technology Program, TIGP, Institute of Chemistry, Academia Sinica, Nankang, Taipei 115, Taiwan
c
Department of Chemistry, National Tsing Hua University, Hsinchu 300, Taiwan
d
Department of Chemistry, Tamkang University, Tamsui, New Taipei City 251, Taiwan
e
Instrumentation Center, National Taiwan University, Taipei 106, Taiwan
Chem. Commun., 2013,49, 4743-4745

DOI: 10.1039/C3CC39008J
Received 17 Dec 2012, Accepted 04 Mar 2013
First published online 04 Mar 2013
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