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School of Chemistry, Physics and Mechanical Engineering, Queensland University of Technology, Brisbane, Australia
E-mail: hy.zhu@qut.edu.au
; Fax: +61 7 3138 1804
; Tel: +61 7 3138 1581
Chem. Commun., 2013,49, 2676-2678
DOI:
10.1039/C3CC38985E
Received
16 Dec 2012,
Accepted
13 Feb 2013
First published online
22 Feb 2013
The direct hydroamination of alkynes driven by visible light can be achieved in high yield and selectivity at ambient temperature using supported gold nanoparticles (AuNPs) as photocatalysts. Aniline molecules interact with visible light activated AuNPs meanwhile alkynes could be activated at active sites on the support. The findings reveal a new green approach for synthesis of fine organic compounds and provide insight into catalyst design for the activation of CC triple bonds and amines.
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