A polyoxometalate (POM)-based {MnIV2MnIII6MnII4} complex with single-molecule magnet (SMM) behaviour was prepared, exhibiting the largest known Mn nuclearity and the most Mn valence states in the POM-based SMM family.
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A polyoxometalate-based single-molecule magnet with a mixed-valent {MnIV2MnIII6MnII4} core
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a
Key Laboratory of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Ren Min Street No. 5268, Changchun, P. R. China
E-mail: liyg658@nenu.edu.cn
E-mail: liyg658@nenu.edu.cn
b
College of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun, P. R. China
c
CNRS, CRPP, UPR 8641, Research team for “Molecular Magnetic Materials”, F-33600 Pessac, France
E-mail: clerac@crpp-bordeaux.cnrs.fr
E-mail: clerac@crpp-bordeaux.cnrs.fr
d
Univ. Bordeaux, CRPP, UPR 8641, F-33600 Pessac, France
Chem. Commun., 2013,49, 2515-2517
DOI: 10.1039/C3CC38981B
Received 16 Dec 2012, Accepted 05 Feb 2013
First published online 06 Feb 2013
Chemical Communications
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