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Issue 25, 2013
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A polyoxometalate-based single-molecule magnet with a mixed-valent {MnIV2MnIII6MnII4} core

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Abstract

A polyoxometalate (POM)-based {MnIV2MnIII6MnII4} complex with single-molecule magnet (SMM) behaviour was prepared, exhibiting the largest known Mn nuclearity and the most Mn valence states in the POM-based SMM family.

Graphical abstract: A polyoxometalate-based single-molecule magnet with a mixed-valent {MnIV2MnIII6MnII4} core

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Publication details

The article was received on 16 Dec 2012, accepted on 05 Feb 2013 and first published on 06 Feb 2013


Article type: Communication
DOI: 10.1039/C3CC38981B
Citation: Chem. Commun., 2013,49, 2515-2517
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    A polyoxometalate-based single-molecule magnet with a mixed-valent {MnIV2MnIII6MnII4} core

    Z. Zhang, S. Yao, Y. Li, H. Wu, Y. Wang, M. Rouzières, R. Clérac, Z. Su and E. Wang, Chem. Commun., 2013, 49, 2515
    DOI: 10.1039/C3CC38981B

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