Supramolecular polymerization in water harnessing both hydrophobic effects and hydrogen bond formation

Christianus M. A. Leenders; Lorenzo Albertazzi; Tristan Mes; Marcel M. E. Koenigs; Anja R. A. Palmans; E. W. Meijer

doi:10.1039/C3CC38949A

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Chemical Communications

Issue 19, 2013

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Supramolecular polymerization in water harnessing both hydrophobic effects and hydrogen bond formation

Christianus M. A. Leenders,^a Lorenzo Albertazzi,^a Tristan Mes,^a Marcel M. E. Koenigs,^a Anja R. A. Palmans*^a and E. W. Meijer*^a

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Institute for Complex Molecular Systems, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands
E-mail: e.w.meijer@tue.nl ;
Fax: +31 (0)40 2451036 ;
Tel: +31 (0)40 2473101

Chem. Commun., 2013,49, 1963-1965

DOI: 10.1039/C3CC38949A
Received 14 Dec 2012, Accepted 18 Jan 2013
First published online 21 Jan 2013

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Abstract
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The formation of supramolecular polymers in water through rational design of a benzene-1,3,5-tricarboxamide (BTA) motif is presented. Intermolecular hydrogen bonding and hydrophobic effects cooperate in the self-assembly into long fibrillar aggregates. Minimal changes in molecular structure significantly affect the internal packing of the aggregates.

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Christianus M. A. Leenders
Lorenzo Albertazzi
Tristan Mes
Marcel M. E. Koenigs
Anja R. A. Palmans
E. W. Meijer

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