A thin film of sodium manganese ferrocyanide, Na1.32Mn[Fe(CN)6]0.83·3.5H2O, exhibits discharge capacity (= 109 mA h g−1) and discharge voltage (3.4 V in average) at 0.5 C against Na in aprotic solvent. The ex situXRD experiments reveal that the host framework remains cubic without showing any structural phase transition during the charge process. The discharge property is discernible up to 40 C.
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