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Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, 3663 N. Zhongshan Road, Shanghai, P. R. China
; Fax: +86 21-6223-4560
; Tel: +86 21-6223-4560
Chem. Commun., 2013,49, 2022-2024
09 Dec 2012,
19 Jan 2013
First published online
23 Jan 2013
We report the first organocatalytic asymmetric synthesis of 3,3-disubstituted oxindoles featuring two heteroatoms at the C3 position. Importantly, 3-thiooxindoles and 3-alkoxyoxindoles are demonstrated to be reactive nucleophiles for the development of catalytic asymmetric reactions for the first time.
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