A four-coordinate thionitrosyl complex of vanadium

Ba L. Tran; Rick Thompson; Soumya Ghosh; Xinfeng Gao; Chun-Hsing Chen; Mu-Hyun Baik; Daniel J. Mindiola

doi:10.1039/C3CC38799B

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Chemical Communications

Issue 27, 2013

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A four-coordinate thionitrosyl complex of vanadium

Ba L. Tran,^a Rick Thompson,^a Soumya Ghosh,^a Xinfeng Gao,^a Chun-Hsing Chen,^a Mu-Hyun Baik^a and Daniel J. Mindiola*^a

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Department of Chemistry, Indiana University, 800 E. Kirkwood Avenue, Bloomington, USA
E-mail: mindiola@indiana.edu ;
Fax: +1 812 855 8300 ;
Tel: +1 812 855 4798, +1 812 855 2399

Chem. Commun., 2013,49, 2768-2770

DOI: 10.1039/C3CC38799B
Received 07 Dec 2012, Accepted 15 Feb 2013
First published online 18 Feb 2013

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Abstract
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Addition of elemental sulfur to the vanadium nitride [(nacnac)V [triple bond, length as m-dash] N(OAr)] forms the first thionitrosyl complex of vanadium, [(nacnac)V(NS)(OAr)]. Single crystal X-Ray diffraction studies and DFT calculations reveal an almost linear thionitrosyl ligand resulting from an extended π-resonance across the VNS moiety.