A cofacial bis(Mg(II)porphyrin)–C6H4-free base ([Mg2]–bridge–FB) dyad shows S1 energy transfer in both directions and much slower rates than similar monoporphyrin systems are observed.
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Is the special pair structure a good strategy for the kinetics during the last step of the energy transfer with the nearest antenna? A chemical model approach
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a
Institut de Chimie Moléculaire de l'Université de Bourgogne (ICMUB,UMR 6302), Université de Bourgogne, Dijon, France
b
Département de Chimie, Université de Sherbrooke, 2550 Boulevard de l'Université, Sherbrooke, Canada J1K 2R1
E-mail: Pierre.Harvey@USherbrooke.ca ;
Fax: +1-819-821-8017 ;
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E-mail: Pierre.Harvey@USherbrooke.ca ;
Fax: +1-819-821-8017 ;
Tel: +1-819-821-7092
Chem. Commun., 2013,49, 2228-2230
DOI: 10.1039/C3CC38740B
Received 05 Dec 2012, Accepted 26 Jan 2013
First published online 29 Jan 2013
Chemical Communications
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