A unique magnesium-based 3D MOF with nanoscale cages and temperature dependent selective gas sorption properties

Yong-Liang Huang; Yun-Nan Gong; Long Jiang; Tong-Bu Lu

doi:10.1039/C3CC38730E

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Chemical Communications

Issue 17, 2013

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A unique magnesium-based 3D MOF with nanoscale cages and temperature dependent selective gas sorption properties

Yong-Liang Huang,^a Yun-Nan Gong,^a Long Jiang^a and Tong-Bu Lu*^a

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MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
E-mail: lutongbu@mail.sysu.edu.cn ;
Fax: +86-20-84112921

Chem. Commun., 2013,49, 1753-1755

DOI: 10.1039/C3CC38730E
Received 05 Dec 2012, Accepted 14 Jan 2013
First published online 23 Jan 2013

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A porous Mg-based 3D metal–organic framework with unique nanoscale cages and two-fold interpenetrating pcu nets has been synthesized and characterized. It shows gas-uptake capacities for N₂, H₂, O₂ and CO₂ at low temperatures and selective adsorption of CO₂ over O₂ and N₂ at room temperature.

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