Fluorine interaction controlled AIEE phenomenon in an expanded calixbenzophyrin and its vapoluminescent response: turn on emission with volatile ketones and esters

P. S. Salini; M. G. Derry Holaday; M. L. P. Reddy; C. H. Suresh; A. Srinivasan

doi:10.1039/C3CC38723B

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Chemical Communications

Issue 22, 2013

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Fluorine interaction controlled AIEE phenomenon in an expanded calixbenzophyrin and its vapoluminescent response: turn on emission with volatile ketones and esters

P. S. Salini,^a M. G. Derry Holaday,^a M. L. P. Reddy,^b C. H. Suresh*^b and A. Srinivasan*^c

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Photosciences and Photonics Group, Chemical Sciences and Technology Division, CSIR-National Institute for Interdisciplinary Science and Technology (NIIST), Trivandrum 695 019, India

Inorganic Chemistry Section, Chemical Sciences and Technology Division, CSIR-National Institute for Interdisciplinary Science and Technology (NIIST), Trivandrum 695 019, India

School of Chemical Sciences, National Institute of Science Education and Research, IOP Campus, Sainik School – P. O., Bhubaneswar – 751 005, India
E-mail: srini@niser.ac.in ;
Fax: +91 674-2302436

Chem. Commun., 2013,49, 2213-2215

DOI: 10.1039/C3CC38723B
Received 05 Dec 2012, Accepted 23 Jan 2013
First published online 23 Jan 2013

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Fluorine interaction assisted AIEE characteristic in an expanded calixbenzophyrin is presented by single-crystal X-ray-diffraction analysis and molecular modelling approaches. Selective exposure to volatile organic compounds such as ketones and esters results in the breaking of fluorine interaction, leading to enhanced monomer emission.

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P. S. Salini
M. G. Derry Holaday
M. L. P. Reddy
C. H. Suresh
A. Srinivasan

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Fluorine interaction controlled AIEE phenomenon in an expanded calixbenzophyrin and its vapoluminescent response: turn on emission with volatile ketones and esters

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Fluorine interaction controlled AIEE phenomenon in an expanded calixbenzophyrin and its vapoluminescent response: turn on emission with volatile ketones and esters

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