Pd(diimine)Cl2 embedded heterometallic compounds with porous structures as efficient heterogeneous catalysts

Sheng-Li Huang; Ai-Quan Jia; Guo-Xin Jin

doi:10.1039/C3CC38714C

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Chemical Communications

Issue 24, 2013

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Pd(diimine)Cl₂ embedded heterometallic compounds with porous structures as efficient heterogeneous catalysts

Sheng-Li Huang,^a Ai-Quan Jia^b and Guo-Xin Jin*^a

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Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Department of Chemistry, Advanced Materials Laboratory, Fudan University, Shanghai, P. R. China
E-mail: gxjin@fudan.edu.cn

Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma’anshan, P. R. China

Chem. Commun., 2013,49, 2403-2405

DOI: 10.1039/C3CC38714C
Received 04 Dec 2012, Accepted 05 Feb 2013
First published online 06 Feb 2013

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Four porous heterometallic coordination polymers were synthesized via a metalloligand strategy. All of them contain the [Pd(diimine)Cl₂] moiety, which has good catalytic activity, and present remarkable versatility for catalysing Suzuki–Miyaura and Heck reactions.

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Pd(diimine)Cl₂ embedded heterometallic compounds with porous structures as efficient heterogeneous catalysts