A metal templated synthetic approach gives access to [Cp*Fe(CO)2{B(NMesCMe)2CH}][BArf4], and represents the first example of coordinative trapping of the elusive [B(NRCMe)2CH] fragment.
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Coordinative trapping of the boron β-diketiminato system [B(NMesCMe)2CH] via metal-templated synthesis
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Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Rd, Oxford, UK
E-mail: Simon.Aldridge@chem.ox.ac.uk ;
Tel: +44 (0)1865 285201
E-mail: Simon.Aldridge@chem.ox.ac.uk ;
Tel: +44 (0)1865 285201
Chem. Commun., 2013,49, 1509-1511
DOI: 10.1039/C3CC38073D
Received 08 Nov 2012, Accepted 08 Jan 2013
First published online 10 Jan 2013
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