Molecular evidence for the intermolecular SS interaction in the surface molecular packing motifs of a fused thiophene derivative

Xuan-Yun Wang; Wei Jiang; Ting Chen; Hui-Juan Yan; Zhao-Hui Wang; Li-Jun Wan; Dong Wang

doi:10.1039/C3CC37990F

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Chemical Communications

Issue 18, 2013

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Molecular evidence for the intermolecular SS interaction in the surface molecular packing motifs of a fused thiophene derivative

Xuan-Yun Wang,^a^b Wei Jiang,^a Ting Chen,^a Hui-Juan Yan,^a Zhao-Hui Wang,^a Li-Jun Wan^a and Dong Wang*^a

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Institute of Chemistry, Chinese Academy of Sciences, Beijing National Laboratory for Molecular Sciences, Beijing 100190, People's Republic of China
E-mail: wangd@iccas.ac.cn ;
Fax: +86-10-82616935 ;
Tel: +86-10-82616935

University of Chinese Academy of Sciences, Beijing, People's Republic of China

Chem. Commun., 2013,49, 1829-1831

DOI: 10.1039/C3CC37990F
Received 05 Nov 2012, Accepted 16 Jan 2013
First published online 17 Jan 2013

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A microscopic investigation of the molecular packing structures of a fused thiophene derivative reveals the important role of intermolecular SS interaction in directing the 2D self-assembly. Thermal annealing of the assembly results in the irreversible phase transition to a new structure with different molecular trimeric packing motifs.