Fe3O4@coordination polymer microspheres with self-supported polyoxometalates in shells exhibiting high-performance supercapacitive energy storage

Shuai Xu; Lijun You; Peng Zhang; Yuting Zhang; Jia Guo; Changchun Wang

doi:10.1039/C3CC37977A

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Chemical Communications

Issue 24, 2013

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Fe₃O₄@coordination polymer microspheres with self-supported polyoxometalates in shells exhibiting high-performance supercapacitive energy storage

Shuai Xu,^a Lijun You,^a Peng Zhang,^a Yuting Zhang,^a Jia Guo*^a and Changchun Wang^a

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State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, and Laboratory of Advanced Materials, Fudan University, Shanghai 200433, P. R. China
E-mail: guojia@fudan.edu.cn ;
Fax: +86-21-6564-0293 ;
Tel: +86-21-51630304

Chem. Commun., 2013,49, 2427-2429

DOI: 10.1039/C3CC37977A
Received 04 Nov 2012, Accepted 04 Feb 2013
First published online 06 Feb 2013

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An exquisitely structured CPP consisting of a self-supported POM-Zn(II) coordination polymer as the shell and a Fe₃O₄ cluster as the core was synthesized, which could be fabricated as a supercapacitive film electrode showing prominent electrochemical activities for enormous energy storage.

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Shuai Xu
Lijun You
Peng Zhang
Yuting Zhang
Jia Guo
Changchun Wang

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Fe₃O₄@coordination polymer microspheres with self-supported polyoxometalates in shells exhibiting high-performance supercapacitive energy storage