Jump to main content
Jump to site search

Issue 16, 2013
Previous Article Next Article

Enhancement of CO2 selectivity in a pillared pcu MOM platform through pillar substitution

Author affiliations

Abstract

Pillar substitution in a long-known metal–organic material with saturated metal centres, [Cu(bipy)2(SiF6)]n, has afforded the first crystallographically characterized porous materials based upon TiF62− and SnF62− anions as pillars. Gas adsorption studies revealed similar surface areas and adsorption isotherms but enhanced selectivity towards CO2vs. CH4 and N2.

Graphical abstract: Enhancement of CO2 selectivity in a pillared pcu MOM platform through pillar substitution

Back to tab navigation

Supplementary files

Publication details

The article was received on 22 Oct 2012, accepted on 08 Jan 2013 and first published on 09 Jan 2013


Article type: Communication
DOI: 10.1039/C3CC37695H
Citation: Chem. Commun., 2013,49, 1606-1608
  •   Request permissions

    Enhancement of CO2 selectivity in a pillared pcu MOM platform through pillar substitution

    P. Nugent, V. Rhodus, T. Pham, B. Tudor, K. Forrest, L. Wojtas, B. Space and M. Zaworotko, Chem. Commun., 2013, 49, 1606
    DOI: 10.1039/C3CC37695H

Search articles by author

Spotlight

Advertisements