Issue 16, 2013

Enhancement of CO2 selectivity in a pillared pcu MOM platform through pillar substitution

Abstract

Pillar substitution in a long-known metal–organic material with saturated metal centres, [Cu(bipy)2(SiF6)]n, has afforded the first crystallographically characterized porous materials based upon TiF62− and SnF62− anions as pillars. Gas adsorption studies revealed similar surface areas and adsorption isotherms but enhanced selectivity towards CO2vs. CH4 and N2.

Graphical abstract: Enhancement of CO2 selectivity in a pillared pcu MOM platform through pillar substitution

Supplementary files

Article information

Article type
Communication
Submitted
22 Oct 2012
Accepted
08 Jan 2013
First published
09 Jan 2013

Chem. Commun., 2013,49, 1606-1608

Enhancement of CO2 selectivity in a pillared pcu MOM platform through pillar substitution

P. Nugent, V. Rhodus, T. Pham, B. Tudor, K. Forrest, L. Wojtas, B. Space and M. Zaworotko, Chem. Commun., 2013, 49, 1606 DOI: 10.1039/C3CC37695H

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