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Issue 34, 2013
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Organic multishell isostructural host–guest crystals: fullerenes C60 inside a nitroxide open framework

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Abstract

The dinitroxide biradical bTbk crystallizes forming hexagonal open frameworks with one-dimensional corrugated channels filled with crystallization solvent. The large pockets constitutive of the channels allowed the inclusion of C60 in the paramagnetic network. The rapidity and high fidelity of crystal growth were used to prepare isostructural multilayer host–guest crystals successively stained with C60.

Graphical abstract: Organic multishell isostructural host–guest crystals: fullerenes C60 inside a nitroxide open framework

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Publication details

The article was received on 08 Jan 2013, accepted on 07 Mar 2013 and first published on 07 Mar 2013


Article type: Communication
DOI: 10.1039/C3CC00170A
Citation: Chem. Commun., 2013,49, 3519-3521
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    Organic multishell isostructural host–guest crystals: fullerenes C60 inside a nitroxide open framework

    D. Bardelang, M. Giorgi, C. Pardanaud, V. Hornebecq, E. Rizzato, P. Tordo and O. Ouari, Chem. Commun., 2013, 49, 3519
    DOI: 10.1039/C3CC00170A

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