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NMR Research Centre, Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore-560012, India
E-mail: nsp@sif.iisc.ernet.in
; Fax: +91 80 23601550
; Tel: +91 80 22933300
Chem. Commun., 2013,49, 2049-2051
DOI:
10.1039/C3CC00045A
Received
03 Jan 2013,
Accepted
28 Jan 2013
First published online
28 Jan 2013
A novel weakly ordered chiral lyotropic alignment medium, derived by the self-assembly of guanosine 5′-monophosphate (5′-GMP):guanosine for scaling RDCs to desired strengths and for the discrimination of enantiomers, is reported. The preparation of this inexpensive mesophase is straightforward, requires less time (1 h), and is sustainable, reversible and tunable over a wide range of temperature (280–330 K) and concentration.
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