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Issue 23, 2013
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Generation and alkylation of 2-boryl allylic sulfone anions

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Abstract

The deprotonation and electrophilic trapping of an allylic sulfone substituted at the 2 position by a pinacol boronate results in the formation of the corresponding alkylation products. The ability of the boronate ester to tolerate the sulfonyl carbanion suggests a broader application of the methodology to prepare a wide range of functionalized boronates.

Graphical abstract: Generation and alkylation of 2-boryl allylic sulfone anions

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Publication details

The article was received on 02 Jan 2013, accepted on 05 Feb 2013 and first published on 08 Feb 2013


Article type: Communication
DOI: 10.1039/C3CC00030C
Citation: Chem. Commun., 2013,49, 2365-2367
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    Generation and alkylation of 2-boryl allylic sulfone anions

    E. F. Altenhofer and M. Harmata, Chem. Commun., 2013, 49, 2365
    DOI: 10.1039/C3CC00030C

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