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Issue 21, 2013
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Aminocatalyzed asymmetric Diels–Alder reaction of 2,4-dienals and rhodanine/hydantoin derivatives

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Abstract

Aminocatalyzed asymmetric Diels–Alder reaction between 2,4-dienals and rhodanine/hydantoin derivatives via trienamine mechanism has been developed to synthesize various spirocyclic compounds with good yields (up to 98%) and excellent stereoselectivities (up to 99% ee and >19 : 1 dr).

Graphical abstract: Aminocatalyzed asymmetric Diels–Alder reaction of 2,4-dienals and rhodanine/hydantoin derivatives

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Publication details

The article was received on 02 Jan 2013, accepted on 23 Jan 2013 and first published on 07 Feb 2013


Article type: Communication
DOI: 10.1039/C3CC00023K
Citation: Chem. Commun., 2013,49, 2157-2159
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    Aminocatalyzed asymmetric Diels–Alder reaction of 2,4-dienals and rhodanine/hydantoin derivatives

    K. Zhu, H. Huang, W. Wu, Y. Wei and J. Ye, Chem. Commun., 2013, 49, 2157
    DOI: 10.1039/C3CC00023K

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