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Issue 13, 2013
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Zn-mediated asymmetric allylation of N-tert-butanesulfinyl ketimines: an efficient and practical access to chiral quaternary 3-aminooxindoles

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Abstract

Room temperature zinc-mediated diastereoselective allylation or propargylation of isatin-derived N-tert-butanesulfinyl ketimines for synthesis of highly enantiomerically enriched tetrasubstituted 3-aminooxindoles is described.

Graphical abstract: Zn-mediated asymmetric allylation of N-tert-butanesulfinyl ketimines: an efficient and practical access to chiral quaternary 3-aminooxindoles

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Publication details

The article was received on 30 Nov 2012, accepted on 21 Dec 2012 and first published on 21 Dec 2012


Article type: Communication
DOI: 10.1039/C2CC38600C
Citation: Chem. Commun., 2013,49, 1327-1329
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    Zn-mediated asymmetric allylation of N-tert-butanesulfinyl ketimines: an efficient and practical access to chiral quaternary 3-aminooxindoles

    D. Chen and M. Xu, Chem. Commun., 2013, 49, 1327
    DOI: 10.1039/C2CC38600C

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