By introducing a third arm with two anionic carboxylate groups, a water-soluble bis(m-phenylene)-32-crown-10-based cryptand was synthesized. Its pH-controlled host–guest complexation with a paraquat derivative in water was studied.
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Synthesis of a water-soluble bis(m-phenylene)-32-crown-10-based cryptand and its pH-responsive binding to a paraquat derivative
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MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Chemistry, Zhejiang University, 310027 Hangzhou, P. R. China
E-mail: fhuang@zju.edu.cn ;
Fax: +86-571-8795-3189 ;
Tel: +86-571-8795-3189
E-mail: fhuang@zju.edu.cn ;
Fax: +86-571-8795-3189 ;
Tel: +86-571-8795-3189
Chem. Commun., 2013,49, 1178-1180
DOI: 10.1039/C2CC38472H
Received 25 Nov 2012, Accepted 18 Dec 2012
First published online 19 Dec 2012
Chemical Communications
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