Department of Applied Biology and Chemical Technology and the State Key Laboratory of Chirosciences, The Hong Kong Polytechnic University, Hunghom, Kowloon, China
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Chem. Commun., 2013,49, 710-712
04 Sep 2012,
03 Dec 2012
First published online
11 Dec 2012
A dinuclear ruthenium catalyst with a rigid anthracene spacer shows excellent regio- and stereo-selectivity in the atom-economic addition of aliphatic carboxylic acids to phenylacetylene, producing exclusively anti-Markovnikov enol-esters with high E/Z ratios of the isomers.
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