Issue 7, 2013

A dinuclear ruthenium catalyst with a confined cavity: selectivity in the addition of aliphatic carboxylic acids to phenylacetylene

Abstract

A dinuclear ruthenium catalyst with a rigid anthracene spacer shows excellent regio- and stereo-selectivity in the atom-economic addition of aliphatic carboxylic acids to phenylacetylene, producing exclusively anti-Markovnikov enol-esters with high E/Z ratios of the isomers.

Graphical abstract: A dinuclear ruthenium catalyst with a confined cavity: selectivity in the addition of aliphatic carboxylic acids to phenylacetylene

Supplementary files

Article information

Article type
Communication
Submitted
04 Sep 2012
Accepted
03 Dec 2012
First published
11 Dec 2012

Chem. Commun., 2013,49, 710-712

A dinuclear ruthenium catalyst with a confined cavity: selectivity in the addition of aliphatic carboxylic acids to phenylacetylene

K. Cheung, W. Wong, M. So, Z. Zhou, S. Yan and K. Wong, Chem. Commun., 2013, 49, 710 DOI: 10.1039/C2CC38454J

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