Dual emissive borane–BODIPY dyads: molecular conformation control over electronic properties and fluorescence response towards fluoride ions

Chinna Ayya Swamy P; Sanjoy Mukherjee; Pakkirisamy Thilagar

doi:10.1039/C2CC38352G

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Chemical Communications

Issue 10, 2013

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Dual emissive borane–BODIPY dyads: molecular conformation control over electronic properties and fluorescence response towards fluoride ions

Chinna Ayya Swamy P,^a Sanjoy Mukherjee^a and Pakkirisamy Thilagar*^a

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Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, India
E-mail: thilagar@ipc.iisc.ernet.in ;
Fax: 0091-80-23601552 ;
Tel: 0091-80-22933353

Chem. Commun., 2013,49, 993-995

DOI: 10.1039/C2CC38352G
Received 14 Sep 2012, Accepted 07 Dec 2012
First published online 10 Dec 2012

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Abstract
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Facile synthesis of two new dimesitylboryl appended BODIPYs is reported. The two dyads have similar fluorescent chromophores but differ in their molecular conformations. They exhibit dual fluorescence, intramolecular energy transfer between boryl and BODIPY chromophores and different fluorescence responses (emission enhancement and quenching) upon fluoride binding.

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Dual emissive borane–BODIPY dyads: molecular conformation control over electronic properties and fluorescence response towards fluoride ions

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