The transfer of the anionic Ph2P(BH3)–CH–P(BH3)Ph2 ligand from potassium to barium results in the subsequent formation of a tetranuclear barium cluster which contains the hitherto unknown isomeric form Ph2P–CH(BH3)–P(BH3)Ph2 of the ligand.
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Formation of a Ph2PCH(BH3)P(BH3)Ph2 ligand via formal 1,2-borane migration
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a
Institute of Inorganic and Analytical Chemistry, Friedrich-Schiller-University Jena, Humboldtstraße 8, D-07743 Jena, Germany
E-mail: j.langer@uni-jena.de ;
Fax: +49 3641 948132 ;
Tel: +49 3641 948126
E-mail: j.langer@uni-jena.de ;
Fax: +49 3641 948132 ;
Tel: +49 3641 948126
b
Laboratorium für Physikalische Chemie, ETH Zürich, Wolfgang-Pauli-Str. 10, CH-8093 Zürich, Switzerland
E-mail: markus.reiher@phys.chem.ethz.ch ;
Fax: +41 44 633 15 ;
Tel: +41 44 633 43 08
E-mail: markus.reiher@phys.chem.ethz.ch ;
Fax: +41 44 633 15 ;
Tel: +41 44 633 43 08
Chem. Commun., 2013,49, 1121-1123
DOI: 10.1039/C2CC38098F
Received 18 Oct 2012, Accepted 30 Nov 2012
First published online 06 Dec 2012
Chemical Communications
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