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Issue 9, 2013
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Catalytic highly enantioselective vinylogous Povarov reaction

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Abstract

The first example of a catalytic asymmetric vinylogous Povarov reaction is presented. 1-N-Acylamino-1,3-butadienes react selectively at their terminal double bond in the presence of a chiral phosphoric acid catalyst, delivering highly enantioenriched 1,2,3,4-tetrahydroquinolines bearing a synthetically versatile enecarbamate group at the 4-position.

Graphical abstract: Catalytic highly enantioselective vinylogous Povarov reaction

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Publication details

The article was received on 05 Nov 2012, accepted on 06 Dec 2012 and first published on 07 Dec 2012


Article type: Communication
DOI: 10.1039/C2CC38002A
Citation: Chem. Commun., 2013,49, 880-882
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    Catalytic highly enantioselective vinylogous Povarov reaction

    L. Caruana, M. Fochi, S. Ranieri, A. Mazzanti and L. Bernardi, Chem. Commun., 2013, 49, 880
    DOI: 10.1039/C2CC38002A

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