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Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamada-oka, Suita, Japan
E-mail: moriuchi@chem.eng.osaka-u.ac.jp
; Fax: +81-6-6879-7415
; Tel: +81-6-6879-7413
Chem. Commun., 2013,49, 1163-1165
DOI:
10.1039/C2CC37706C
Received
23 Oct 2012,
Accepted
04 Dec 2012
First published online
06 Dec 2012
The synthesis and characterisation of a dinuclear pyridinedicarboxamide–platinum(II) complex exhibiting tunable optical properties based on metal–metal interaction are reported. Conformational change-induced switching between metal-to-ligand charge-transfer and metal–metal-to-ligand charge-transfer emission properties by the influence of methanol was demonstrated.
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