Jump to main content
Jump to site search

Issue 9, 2013
Previous Article Next Article

Synthesis and ferrimagnetic properties of an unprecedented polynuclear cobalt complex composed of [Co24] macrocycles

Author affiliations

Abstract

An unprecedented polynuclear cobalt complex with a [Co24] macrocycle in the presence of [Co(H2O)6]2+ has been prepared and characterized. In this complex, [Co(H2O)6]2+ not only acts as a counterion to balance the negative charge of the 2D layer, but may also serve as a template in the assembly of the [Co24] macrocyclic complex through hydrogen-bond interactions. Magnetic analyses indicate that the title compound shows homometallic ferrimagnetic behavior.

Graphical abstract: Synthesis and ferrimagnetic properties of an unprecedented polynuclear cobalt complex composed of [Co24] macrocycles

Back to tab navigation

Supplementary files

Publication details

The article was received on 18 Oct 2012, accepted on 07 Dec 2012 and first published on 10 Dec 2012


Article type: Communication
DOI: 10.1039/C2CC37593A
Citation: Chem. Commun., 2013,49, 871-873
  •   Request permissions

    Synthesis and ferrimagnetic properties of an unprecedented polynuclear cobalt complex composed of [Co24] macrocycles

    S. Han, W. Song, J. Zhao, Q. Yang, S. Liu, Y. Li and X. Bu, Chem. Commun., 2013, 49, 871
    DOI: 10.1039/C2CC37593A

Search articles by author

Spotlight

Advertisements