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Issue 7, 2013
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Rhodium-catalyzed tandem Pauson–Khand type reactions of 1,4-enynes tethered by a cyclopropyl group

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Abstract

The tandem Pauson–Khand type reactions of 1,4-enynes tethered by a cyclopropyl group with two molecules of CO proceed smoothly in the presence of [Rh(CO)2Cl]2 under a CO atmosphere to give the corresponding 6-hydroxy-2,3-dihydro-1H-inden-1-one derivatives in moderate yields under mild conditions.

Graphical abstract: Rhodium-catalyzed tandem Pauson–Khand type reactions of 1,4-enynes tethered by a cyclopropyl group

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Publication details

The article was received on 18 Oct 2012, accepted on 26 Nov 2012 and first published on 27 Nov 2012


Article type: Communication
DOI: 10.1039/C2CC37587G
Citation: Chem. Commun., 2013,49, 698-700
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    Rhodium-catalyzed tandem Pauson–Khand type reactions of 1,4-enynes tethered by a cyclopropyl group

    G. Chen and M. Shi, Chem. Commun., 2013, 49, 698
    DOI: 10.1039/C2CC37587G

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