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Issue 5, 2013
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Antiferromagnetic ordering through a hydrogen-bonded network in the molecular solid CuF2(H2O)2(3-chloropyridine)

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Abstract

CuF2(H2O)2(3-chloropyridine) possesses a five-coordinate Cu2+ center with a slightly distorted trigonal bypyramidal coordination geometry. Strong intermolecular F⋯H–O hydrogen bonds enable the formation of 2D layers and provide the primary magnetic exchange path that leads to the stabilization of long-range antiferromagnetic (AFM) order below TN = 2.1 K.

Graphical abstract: Antiferromagnetic ordering through a hydrogen-bonded network in the molecular solid CuF2(H2O)2(3-chloropyridine)

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Publication details

The article was received on 12 Oct 2012, accepted on 18 Nov 2012, published on 20 Nov 2012 and first published online on 20 Nov 2012


Article type: Communication
DOI: 10.1039/C2CC37444G
Citation: Chem. Commun., 2013,49, 499-501
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    Antiferromagnetic ordering through a hydrogen-bonded network in the molecular solid CuF2(H2O)2(3-chloropyridine)

    S. H. Lapidus, J. L. Manson, H. Park, A. J. Clement, S. Ghannadzadeh, P. Goddard, T. Lancaster, J. S. Möller, S. J. Blundell, M. T. F. Telling, J. Kang, M. Whangbo and J. A. Schlueter, Chem. Commun., 2013, 49, 499
    DOI: 10.1039/C2CC37444G

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