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Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560 012, India
E-mail: psm@ipc.iisc.ernet.in
; Fax: +91-80-2360-1552
; Tel: +91-80-2293-3352
Chem. Commun., 2013,49, 4307-4309
DOI:
10.1039/C2CC37377G
Received
09 Oct 2012,
Accepted
17 Dec 2012
First published online
18 Dec 2012
Unique three-component self-assembly of a cis-blocked 90° Pd(II) acceptor with a mixture of tri- and tetra-imidazole donors led to the self-sorting of a Pd7 molecular boat with an internal nanocavity, which catalyses the Knoevenagel condensation of a series of aromatic aldehydes with 1,3-dimethylbarbituric acid and Meldrum's acid in aqueous media.
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