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Issue 39, 2013
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Rhodium-catalyzed cysteine modification with diazo reagents

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Abstract

A simple rhodium(II) complex catalyzes cysteine modification with diazo reagents. The reaction is marked by clean cysteine selectivity and mild reaction conditions. The resulting linkage is significantly more stable in human plasma serum, when compared to common maleimide reagents.

Graphical abstract: Rhodium-catalyzed cysteine modification with diazo reagents

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Supplementary files

Publication details

The article was received on 08 Oct 2012, accepted on 12 Nov 2012 and first published on 13 Nov 2012


Article type: Communication
DOI: 10.1039/C2CC37323H
Citation: Chem. Commun., 2013,49, 4166-4168
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    Rhodium-catalyzed cysteine modification with diazo reagents

    R. Kundu and Z. T. Ball, Chem. Commun., 2013, 49, 4166
    DOI: 10.1039/C2CC37323H

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